John & Beverley Charman -$95 Million
When John Charman was married to his childhood sweetheart Beverley, he was pretty much a broke man. During the course of their 29-year union, however, he was able to become the eighth richest man in London. She eventually let her job go so that she could focus on raising their kids. When they split up, Beverley got a settlement amounting to $95 million.

John & Beverley Charman -$95 Million
Arnold Schwarzenegger & Maria Shriver – $375 Million
Arnold Schwarzenegger and Maria Shriver had been man and wife for 25 years when they got a divorce. It was a messy affair that was brought about by the revelation of Arnold’s infidelity. They signed no prenuptial agreement, and this was why Maria walked away with $375 million and custody of their kids.

Arnold Schwarzenegger & Maria Shriver – $375 Million