Demi Moore & Ashton Kutcher
Demi Moore and Ashton Kutcher had been dating for two years when they walked down the aisle in 2005. In 2011, they decided to go their own ways and the following year, Kutcher filed for divorce. They pointed to irreconcilable differences for the separation. The details of the settlement were never disclosed, though rumor has it that Kutcher coughed up more than he should have had.
John & Beverley Charman -$95 Million
When John Charman was married to his childhood sweetheart Beverley, he was pretty much a broke man. During the course of their 29-year union, however, he was able to become the eighth richest man in London. She eventually let her job go so that she could focus on raising their kids. When they split up, Beverley got a settlement amounting to $95 million.